Voltage from wood

As Ingo Burgert and his team at ETH Zurich and Empa have proven time and again: wood is so much more than just a building material. Their research is geared to enhancing the properties of wood to fit it for entirely new applications. For instance, they have already developed high-​strength, water-​repellent and magnetisable wood.

Now, together with the Empa research group led by Francis Schwarze, the team has used one chemical and one biological process to generate electrical voltage from a type of wood sponge. In doing so, they amplify what is known as the “piezoelectric effect” of wood.

Compression creates voltage  

When a piezoelectric material is elastically deformed, it generates an electrical voltage. Measurement technology, in particular, exploits this phenomenon by using sensors that generate a charge signal when mechanically stressed. However, many of the materials often used for these sensors are unsuitable for biomedical applications. Lead zirconate titanate (PZT), for example, cannot be used on the skin due to its toxic lead, and must be specially disposed of.

Wood also has a natural piezoelectric effect, but only generates a very low electrical voltage. If one wants to increase the voltage, the chemical composition of the wood must be changed – and this also makes it more compressible.

From block to sponge

In order to convert wood into an easily formable material, one component of the cell walls must be dissolved out. Wood cell walls consist of three basic substances: lignin, hemicellulose and cellulose. “Lignin is the stabilising substance that trees need to grow tall. Without lignin, which connects the cells and prevents the stiff cellulose fibrils from buckling, this would not be possible,” states Burgert.

A few months ago, Jianguo Sun, a doctoral student in Burgert’s team, together with colleagues from ETH and Empa, showed in a study published in ACS Nano how wood can be made deformable if the lignin is removed chemically. As a result, its piezoelectric effect is enhanced.

The researchers achieved this “delignification” by placing wood in a mixture of hydrogen peroxide and acetic acid. The acid dissolves the lignin, leaving a framework of cellulose layers. “The process retains the hierarchical structure of wood and prevents disassembly of the individual fibres,” Burgert explains.

In this way, a piece of balsa wood becomes a white, wooden sponge, made up of layer upon layer of thin cellulose. The sponge can simply be compressed and then returns to its original shape. “The wood sponge generates an electrical voltage 85 times higher than that of native (untreated) wood,” says Sun.

A mini-​generator in the wooden floor